In this work, activated carbon nanofiber (ACNF) electrodes with high double-layer capacitance and good rate capability were prepared from polyacrylonitrile nanofibers by optimizing the carbonization temperature prior to H2O activation. The morphology of the ACNFs was observed by scanning electron microscopy. The elemental composition was determined by analysis of X-ray photoelectron spectroscopy. N2-adsorption-isotherm characteristics at 77 K were confirmed by Brunauer-Emmett-Teller and Dubinin-Radushkevich equations. ACNFs processed at different carbonization temperatures were applied as electrodes for electrical double-layer capacitors. The experimental results showed that the surface morphology of the CNFs was not significantly changed after the carbonization process, although their diameters gradually decreased with increasing carbonization temperature. It was found that the carbon content in the CNFs could easily be tailored by controlling the carbonization temperature. The specific capacitance of the prepared ACNFs was enhanced by increasing the carbonization temperature.
Super-capacitors, as energy storage devices with high power density and long cycle life, have attracted great attention in recent years because of their potential in applications such as portable devices, electric vehicles, transportation, and digital communication systems [1-3]. According to the energy storage mechanism used, super-capacitors can be divided into two classes. The function of electric double-layer capacitors depends on the pore structure of the electrode materials and that of pseudo-capacitors is based on active electrode materials in which the faradic redox process occurs. To develop super-capacitors with high performance, various materials have been examined as possible electrode materials. Among them, activated carbon powders [4,5] and fibers [6-8]; which have high porosity, a large surface area, and good conductivity, have been used most widely.
Activated carbon nanofibers (ACNFs) are well known as materials with a number of significant advantages over conventional powders. ACNFs are microporous carbonaceous adsorbents developed from organic precursors, by either physical or chemical activation [9-14]. The advantages of ACNFs are smaller fiber diameter, more concentrated pore-size distribution, and excellent adsorption capacity at low concentrations, in comparison with conventional activated granular or powdered carbons .
The type of porosity is mainly determined by the type of precursor employed; however, the method of activation is a key parameter which may influence the final pore-size distribution . Carbonization temperature is another variable which has a large effect on pore-volume evolution [15-17]. High carbonization temperature results in a greater amount of volatiles being released from the raw material, and eventually influences the product yield and porosity .
In this work, polyacrylonitrile (PAN)-based ACNF electrodes with high capacitance and good rate capability were prepared by optimizing the carbonization temperature prior to H2O activation.
PAN nanofibers (Amotech, Korea) were used as the starting material. The nanofibers were heated to 800-1000℃ at 5℃/min in a SiC furnace under nitrogen (99.999%), and kept at a target temperature for 2 h to obtain carbonized nanofibers. Then, the gas flow was switched to H2O at a rate of 0.5 mL/min while the temperature was raised to 1000℃ and held for 20 min. ACNFs series were obtained after cool-down to room temperature.
The nitrogen adsorption isotherms of CNFs and ACNFs were measured with BELSORP-max (BEL Japan, Japan) at liquid-nitrogen temperature. All samples were degassed at 300℃ for 6 h prior to measurement. The specific surface area was calculated in the relative pressure interval of 0.04-0.2 using the Brunauer-Emmett-Teller method . Micro size was calculated by the Dubinin-Radushkevich equation from adsorption curves [19,20]. The morphology of CNF-800, CNF-850, CNF-900, and CNF-950 were explored using a field-emission scanning electron microscope (JSM 6701-F, JEOL, Japan). To reduce charging during scanning electron microscopy (SEM) imaging, the samples were first placed on a sample holder and coated with platinum. Diameter distributions of the nanofibers were determined by measuring 100 nanofibers from different regions of each SEM image. X-Ray diffraction spectra were obtained using a PHI 5000 VersaProbe II (ULVAC-PHI, Japan) diffractometer with a thin-film attachment. A Cu Kα1 X-ray source was used at 40 kV and 126 mA.
The capacitive performance of the as-prepared samples was investigated in 1 M organic electrolyte [1 M (C2H5)4NBF4/ propylene carbonate] solution using a coin-type two-electrode testing cell. The electrodes were prepared by mixing the carbon samples with carboxymethyl cellulose, styrene butadiene rubber , and commercial carbon. The slurries were rolled into a membrane and then pressed onto Al-mesh current collectors. Thereafter, the electrodes were dried at 120℃ for 24 h in an oven. Each electrode was fabricated by pressing the ACNF-coated film between two circular pieces of Al mesh. A two-electrode configuration was used to measure electrochemical performance.
The fifth cycle of galvanostatic charge/discharge was used to evaluate the electrochemical performance of the samples. The specific capacitance was calculated from data generated during the charge/discharge tests, based on the following equation:
where i is the discharge current (A), Δt is the discharge time (s), m is the mass of electrode (g), and ΔV is the potential difference (V).
The microstructure of the prepared CNFs is shown in Fig. 1. The surfaces of all the CNFs were typically very smooth, without any pores, but with some uneven surfaces. The average diameter of the CNFs obtained from this experiment was estimated by ImageJ software (JEOL, Japan), installed in the SEM apparatus. As can be seen in Fig. 2, the PAN nanofibers diameter is relatively uniform (710 nm). The diameters of the PAN nanofibers decreased slightly during carbonization. Fig. 2b shows CNF-800: the average diameter of fibers being around 670 nm. The diameter of the CNFs decreased with increasing carbonization temperature. It was found that the diameter of the fibers decreased to around 640 nm as a result of carbonization at the temperature of 950℃.
The chemical composition of the CNFs carbonized at different activation temperatures were evaluated by X-ray photoelectron spectroscopy elemental analysis and listed in Table 1. The carbon content was determined to be 84.28, 85.44, 87.48, and 89.13% for the CNFs samples carbonized at 800, 850, 900 and 950℃, respectively. It was found that the carbon content of the CNFs decreased with increasing carbonization temperature. High carbonization temperature results in a greater amount of volatiles being released from the raw material.
The specific surface area and pore structures of the ACNFs before and after activation are shown in Table 2. The specific surface area of the CNFs increased with H2O activation. The specific surface area of CNFs decreased with increasing carbonization temperature. If the carbonization temperature was increased, the specific surface area increased to equal that of ACNF-850 (electrode carbonized at 850℃) and then decreased. Total pore-volume showed a similar trend. The ACNF-900 sample showed better-developed mesopores than did the ACNF-850 and ACNF-950 samples. This means that a moderate carbonization temperature results in larger pore size.
It is clear that the surface area and pore structure are significantly influenced by the carbonization temperature. The specific surface area of the ACNFs varied between 850 and 1710 m2/g. It reached a maximum value of 1710 m2/g at 850℃, indicating that moderate carbonization is beneficial for obtaining high-surfacearea ACNFs.
The manufacture of ACNFs by H2O activation involves two steps: carbonization of the precursor under an inert gas, and activation of carbonized webs in H2O. In the carbonization step, the resulting char becomes rich in carbon and the fundamental sysporous structure is generated by eliminating non-carbon atoms. Meanwhile, the microcrystalline structure of the char is rearranged, resulting in a well-ordered structure. This rearrangement hinders the subsequent activation reaction. For these reasons, carbonization cannot be accomplished at a low temperature. On the other hand, carbonization at a high temperature may make the structure of the carbonized webs too well-ordered to be easily gasified.
The electrochemical properties of the ACNF electrodes, including galvanostatic charge/discharge, were studied using propylene carbonate solution as electrolyte. Fig. 3 shows typical galvanostatic charge/discharge curves, of the specific capacitance in relation to current density, of ACNF electrodes carbonized at various temperatures. Based on the results of charge– discharge cycling, the specific discharge capacitance increased with increasing mesopore volume. The curves are almost linear and discharge time gradually increases with increasing carbonization temperature. The specific capacitance of the samples carbonized at temperatures of 800, 850, 900 and 950℃; is about 16.5, 19.5, 24.2 and 28.1 F/g, respectively. Normally, the specific capacitance of the ACNFs exhibits a strong relationship with their mesoporosity
In this work, ACNF electrodes with high double-layer capacitance and good rate capability were prepared from PAN nanofibers by optimizing the carbonization temperature prior to H2O activation. The carbonization temperature has a marked effect on the specific surface area, the pore volume, and the electrochemical performance of ACNFs. An increase of the carbonization temperature induces higher specific surface area and larger pore size, which result in higher capacitance and better rate capability. From the charge-discharge characteristics, ACNF- 950 showed the best result (28.1 F/g), among all the activated samples.